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Classic Who recs?
So I have a as-nearly-complete-as-these-things-can-be collection of Classic Doctor Who, and no idea where to start. I would like to hear your favorite episodes and arcs! Also, I am bringing a selection to a couple of lesbian fangirls, so any femslash fodder would be great. Recommendations?

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If you like starting as early as possible, The Tomb of the Cybermen is a great early episode and a pretty good introduction to the Second Doctor and Jamie.
If you've heard great things about Tom Baker, I liked The Ark in Space and The Pyramids of Mars as starting points.
For the Fifth Doctor, Tegan and Nyssa are pretty femslashy, and you could do worse than starting with Castrovalva. Or that whole three-episode arc, starting back with Four, The Keeper of Traken/Logopolis/Castrovalva make kind of a complete story.
But if you want all of the femslash and fast-moving episodes, Seven and Ace are your best bet. They're sometimes cheesy or hard to follow, but give The Happiness Patrol, The Greatest Show in the Galaxy, Battlefield, and Survival a shot.
And in case it matters, my favorite Third Doctor episode is probably Inferno (aka Doctor Who versus the fascist lava werewolves,) my favorite Sixth Doctor episode is The Mysterious Planet (or the first part of Trial of a Time Lord,) and my favorite First Doctor episode is probably The War Machines.
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I could to give you recs from other eras but they'd tend to be more problematic. (1st Doctor serial "The Romans" is really fun, for instance, but could use a Rape Humour warning.)
If you want a quick taste from the Fifth Doctor era, there's "Black Orchid", as a really short two-part historical, which has Sarah Sutton in two roles.
Also femslashy: Revenge of the Cybermen, while one of the bleak and violent Eric Saward-era serials, has Peri and the all-female Cryons.
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